Hydroperoxide Measurements During Low-Temperature Gas-Phase Oxidation of n-Heptane and n-Decane
نویسندگان
چکیده
منابع مشابه
Low-Temperature Chemical Kinetic and Speciation Studies of n-Heptane
Although there have been many studies of n-heptane ignition, few studies have provided detailed insights into the low-temperature chemistry of n-heptane—a primary reference fuel— through direct measurements of intermediate species formed during ignition. Such measurements provide understanding of reaction pathways that form toxic air pollutants, greenhouse gas emissions, and particulates such a...
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The oxidation of two blends, benzene/n-decane and toluene/n-decane, was studied in a jet-stirred reactor with gas chromatography analysis (temperatures from 500 to 1100 K, atmospheric pressure, stoichiometric mixtures). The studied hydrocarbon mixtures contained 75% of aromatics in order to highlight the chemistry of the low-temperature oxidation of these two aromatic compounds which have a ver...
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The low-temperature oxidation of n-heptane, one of the reference species for the octane rating of gasoline, was investigated using a jet-stirred reactor and two methods of analysis: gas chromatography and synchrotron vacuum ultra-violet photo-ionization mass spectrometry (SVUV-PIMS) with direct sampling through a molecular jet. The second method allowed the identification of products, such as m...
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Hydrogenation reaction with n-heptane on Pt/Al2O3 catalyst was investigated under the steady state condition in a fixed bed reactor. The catalyst was prepared under a variety of conditions, but the one chosen was non-acidic that is not considered a hydrocracking catalyst. The main objective was to vary the selectivity of n-heptane as a function of reaction variables es...
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ژورنال
عنوان ژورنال: The Journal of Physical Chemistry A
سال: 2017
ISSN: 1089-5639,1520-5215
DOI: 10.1021/acs.jpca.6b10378